SM
| Venue: Emirates Stadium |
Arsenal | ||
| G | 22 | David Raya |
| D | 4 | Benjamin White |
| D | 2 | William Saliba |
| D | 6 | Gabriel Magalhães |
| D | 35 | Oleksandr Zinchenko |
| M | 8 | Martin Ødegaard |
| M | 41 | Declan Rice |
| M | 29 | Kai Havertz |
| A | 7 | Bukayo Saka |
| A | 9 | Gabriel Jesus |
| A | 19 | Leandro Trossard |
PSV Eindhoven | ||
| G | 1 | Walter Benítez |
| D | 3 | Jordan Teze |
| D | 6 | Armel Bella-Kotchap |
| D | 18 | Olivier Boscagli |
| D | 8 | Sergiño Dest |
| M | 22 | Jerdy Schouten |
| M | 23 | Joey Veerman |
| M | 11 | Johan Bakayoko |
| M | 34 | Ismael Saibari |
| M | 7 | Noa Lang |
| A | 9 | Luuk de Jong |
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