SM
| Venue: Emirates Stadium |
Arsenal | ||
| G | 30 | Matt Turner |
| D | 3 | Kieran Tierney |
| D | 16 | Rob Holding |
| D | 18 | Takehiro Tomiyasu |
| D | 6 | Gabriel Magalhães |
| M | 34 | Granit Xhaka |
| M | 23 | Albert Sambi Lokonga |
| M | 7 | Bukayo Saka |
| M | 21 | Fábio Vieira |
| A | 9 | Gabriel Jesus |
| M | 14 | Edward Nketiah |
PSV Eindhoven | ||
| G | 1 | Walter Benítez |
| D | 29 | Phillipp Mwene |
| D | 5 | André Ramalho |
| D | 31 | Philipp Max |
| D | 4 | Armando Obispo |
| M | 15 | Érick Gutiérrez |
| M | 6 | Ibrahim Sangaré |
| A | 20 | Guus Til |
| M | 23 | Joey Veerman |
| M | 7 | Xavi Simons |
| M | 11 | Cody Gakpo |
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