SM
| Venue: Emirates Stadium |
Arsenal | ||
| G | 22 | David Raya |
| D | 6 | Gabriel Magalhães |
| D | 4 | Ben White |
| D | 2 | William Saliba |
| D | 33 | Riccardo Calafiori |
| M | 5 | Thomas Partey |
| M | 41 | Declan Rice |
| A | 29 | Kai Havertz |
| A | 19 | Leandro Trossard |
| M | 9 | Gabriel Jesus |
| M | 11 | Gabriel Martinelli |
Shakhtar Donetsk | ||
| G | 31 | Dmytro Riznyk |
| D | 22 | Mykola Matviyenko |
| D | 5 | Valeriy Bondar |
| D | 26 | Yukhym Konoplia |
| D | 13 | Pedrinho |
| M | 11 | Oleksandr Zubkov |
| M | 8 | Dmytro Kryskiv |
| M | 21 | Artem Bondarenko |
| M | 10 | Georgiy Sudakov |
| M | 7 | Eguinaldo |
| A | 14 | Danylo Sikan |
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