SM
| Venue: OPEL Arena |
Mainz 05 | ||
| G | 27 | Robin Zentner |
| CD | 20 | Edimilson Fernandes |
| CD-L | 19 | Moussa Niakhate |
| CD-R | 4 | Jeremiah St. Juste |
| CM-L | 14 | Pierre Kunde S  |
| CM-R | 34 | Bote Baku |
| AM | 5 | Jean-Paul Boëtius S |
| LM | 3 | Aarón Martín |
| RM | 8 | Levin Öztunali |
| CF-L | 28 | Adám Szalai S |
| CF-R | 7 | Robin Quaison |
| Sub | 18 | Daniel Brosinski |
| Sub | 10 | Alexandru Maxim |
| Sub | 9 | Jean-Philippe Mateta |
| Sub | 1 | Florian Müller |
| Sub | 22 | Taiwo Awoniyi |
| Sub | 42 | Alexander Hack |
| Sub | 2 | Ronael Pierre-Gabriel |
| Sub | 35 | Leandro Barreiro |
| Sub | 29 | Jonathan Burkhardt |
Borussia Dortmund | ||
| G | 1 | Roman Bürki |
| CD | 15 | Mats Hummels |
| CD-L | 2 | Dan-Axel Zagadou |
| CD-R | 16 | Manuel Akanji |
| CM-L | 19 | Julian Brandt S |
| CM-R | 33 | Julian Weigl |
| LM | 14 | Nico Schulz |
| RM | 5 | Achraf Hakimi |
| F | 11 | Marco Reus S |
| CF-L | 7 | Jadon Sancho S |
| CF-R | 23 | Thorgan Hazard |
| Sub | 8 | Mahmoud Dahoud |
| Sub | 10 | Mario Götze |
| Sub | 9 | Paco Alcácer |
| Sub | 26 | Lukasz Piszczek |
| Sub | 13 | Raphaël Guerreiro |
| Sub | 34 | Jacob Bruun Larsen |
| Sub | 40 | Eric Oelschlägel |
| Sub | 22 | Mateu Morey |
| Sub | 18 | Leonardo Balerdi |
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