SM
| Venue: Estadio de la Cerámica |
Villarreal | ||
| G | 13 | Andrés Fernández |
| CD-L | 6 | Víctor Ruiz |
| CD-R | 3 | Álvaro |
| LB | 39 | Xavier Quintillá |
| RB | 2 | Mario S  |
| AM | 10 | Vicente Iborra S |
| LM | 19 | Santi Cazorla |
| RM | 5 | Santiago Cáseres S |
| F | 7 | Gerard Moreno |
| AM-L | 8 | Pablo Fornals |
| AM-R | 30 | Samuel Chukwueze |
| Sub | 16 | Alfonso Pedraza |
| Sub | 9 | Carlos Bacca |
| Sub | 28 | Manuel Morlanes |
| Sub | 1 | Sergio Asenjo |
| Sub | 4 | Ramiro Funes Mori |
| Sub | 17 | Karl Toko Ekambi |
| Sub | 22 | Raba |
Valencia | ||
| G | 13 | Neto |
| CD-L | 5 | Gabriel Paulista |
| CD-R | 24 | Ezequiel Garay |
| LB | 14 | José Gayà |
| RB | 4 | Facundo Roncaglia S |
| CM-L | 18 | Daniel Wass |
| CM-R | 10 | Dani Parejo |
| LM | 7 | Gonçalo Guedes |
| RM | 20 | Ferrán Torres S |
| CF-L | 9 | Kevin Gameiro S |
| CF-R | 19 | Rodrigo |
| Sub | 21 | Cristiano Piccini |
| Sub | 17 | Francis Coquelin |
| Sub | 11 | Denis Cheryshev |
| Sub | 28 | Cristian Rivero |
| Sub | 22 | Santi Mina |
| Sub | 12 | Mouctar Diakhaby |
| Sub | 16 | Kang-In Lee |
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