Read how it all unfolded in Sports Mole's minute-by-minute live commentary of the action below.
NAPOLI: Meret; Hysaj, Manolas, Chiriches, Ghoulam; Allan, Elmas, Verdi, Fabian; Mertens, Callejon
BARCA: Ter Stegen; Semedo, Pique, Lenglet, Alba; Alena, Roberto, De Jong; Dembele, Suarez, Griezmann
Other notable statistics have seen both teams ruled offside on one occasion, while Barca have had 12 throw ins to Napoli's five. And Barca eight fouls to Napoli's four.
Barca, meanwhile, have the likes of Rafinha, Busquets, Rakitic, Arthur and Umtiti in reserve tonight. It will be very interesting to see how both managers use their benches here.