SM
| Venue: Emirates Stadium |
Arsenal | ||
| G | 1 | Bernd Leno |
| D | 16 | Rob Holding |
| D | 22 | Pablo Marí |
| D | 2 | Héctor Bellerín |
| M | 32 | Emile Smith Rowe |
| M | 18 | Thomas Partey |
| M | 7 | Bukayo Saka |
| M | 19 | Nicolas Pépé |
| A | 14 | Pierre-Emerick Aubameyang |
| M | 11 | Martin Ødegaard |
| D | 3 | Kieran Tierney |
Villarreal | ||
| G | 13 | Gerónimo Rulli |
| D | 2 | Mario Gaspar |
| D | 3 | Raúl Albiol |
| D | 4 | Pau Torres |
| D | 24 | Alfonso Pedraza |
| M | 5 | Dani Parejo |
| M | 19 | Francis Coquelin |
| M | 14 | Manu Trigueros |
| A | 7 | Gerard Moreno |
| A | 17 | Paco Alcácer |
| M | 11 | Samuel Chukwueze |
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