SM
| Venue: Estadio Camp Nou |
Barcelona | ||
| G | 1 | Marc-André ter Stegen |
| CD-L | 23 | Samuel Umtiti |
| CD-R | 3 | Gerard Piqué |
| LB | 18 | Jordi Alba |
| RB | 20 | Sergi Roberto |
| CM | 5 | Sergio Busquets |
| LM | 7 | Philippe Coutinho S  |
| RM | 4 | Ivan Rakitic S |
| F | 9 | Luis Suárez |
| LF | 11 | Ousmane Dembélé S |
| RF | 10 | Lionel Messi |
| Sub | 15 | Clément Lenglet |
| Sub | 22 | Arturo Vidal |
| Sub | 8 | Arthur |
| Sub | 13 | Jasper Cillessen |
| Sub | 12 | Rafinha |
| Sub | 19 | Munir El Haddadi |
| Sub | 2 | Nélson Semedo |
PSV Eindhoven | ||
| G | 1 | Jeroen Zoet |
| CD-L | 4 | Nick Viergever S |
| CD-R | 5 | Daniel Schwaab |
| LB | 6 | Angeliño |
| RB | 22 | Denzel Dumfries |
| AM | 7 | Gastón Pereiro |
| LM | 8 | Jorrit Hendrix |
| RM | 18 | Pablo Rosario S |
| F | 9 | Luuk de Jong |
| AM-L | 17 | Steven Bergwijn S |
| AM-R | 11 | Hirving Lozano |
| Sub | 2 | Nicolas Isimat-Mirin |
| Sub | 25 | Érick Gutiérrez |
| Sub | 14 | Donyell Malen |
| Sub | 13 | Eloy Room |
| Sub | 20 | Trent Sainsbury |
| Sub | 3 | Aziz Behich |
| Sub | 23 | Bart Ramselaar |
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